A potentially dangerous Request.Form value was detected from the client

Above error comes because by default ASP.Net blocks the possible Script Injection request. e.g. if user type <script>alert('yes');</script> in your text box and when you display the text in text box, this java script will be executed instead of displaying text.

To resolve this problem you need to keep few things in mind:-

1- We can remove HTML Tags from TextBoxes with a simple regular expression filter like this:-
<asp:textbox id="txtSecureTextBox" runat="server" onblur="this.value = this.value.replace(/&lt;\/?[^>]+>/gi, '');">

2- Add ValidateRequest="false" in your Page directive line incase you want to disable this on single page.
<%@ Page Language="C#" AutoEventWireup="true" ValidateRequest="false"/>

3- Incase you want to disable validation through out the site then you can do it in your web.config file like this:-
    <pages validateRequest="false" />  

4- Use HTMLEncode whenever you are displaying unsafe contents in labels like this:-
Label1.Text = Server.HtmlEncode(TextBox1.Text) 

For further details see Request Validation - Preventing Script Attacks.